{"id":605,"date":"2017-04-26T14:59:13","date_gmt":"2017-04-26T14:59:13","guid":{"rendered":"https:\/\/wp0.vanderbilt.edu\/rizzolab\/?page_id=605"},"modified":"2017-12-08T16:01:03","modified_gmt":"2017-12-08T16:01:03","slug":"chem-220a","status":"publish","type":"page","link":"https:\/\/wp0.vanderbilt.edu\/rizzolab\/chem-220a\/","title":{"rendered":"Chem 220a"},"content":{"rendered":"\n\n\n
\n
\n

\u00a0Chem 220A: Section 1<\/b><\/p>\n

Organic Chemistry Lecture (Fall 2009)<\/b><\/p>\n<\/div>\n

\n

T, R: 9:35 – 11:00 AM<\/b><\/p>\n<\/div>\n

\n

SC 4309<\/b><\/p>\n<\/div>\n<\/td>\n

\n
\n

Carmelo J. Rizzo<\/b><\/p>\n

office: SC 7662<\/b><\/p>\n<\/div>\n

\n

Tel.: 322-6100<\/b><\/p>\n<\/div>\n

\n

e-mail: c.j.rizzo@vanderbilt.edu<\/a><\/b><\/p>\n<\/div>\n<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

The Final Exam will be held on Wednesday, December 16 from 9:00 – 11:00 am in room SC 4309. <\/strong><\/p>\n

No alternative final exam date will be offered. <\/strong><\/p>\n

Office hours for Monday and Tuesday (Dec. 14 & 15): 11:00 – 12:00 and 1:00 – 2:00<\/p>\n

Final exam review will be Monday, Dec. 14 at 5:30 -6:30 pm in SC 4327<\/p>\n

You may use a calculator and molecular models on the final exam<\/p>\n

 <\/p>\n

Click here for C. J. Rizzo’s Chem 220b<\/a> page.<\/p>\n

You will need Adobe Acobat Reader<\/a> to view pdf files.<\/p>\n

updated: 12\/.4<\/b>\/2009<\/b><\/p>\n

Questions & Answers Page:<\/span><\/b>
\nI am posting questions and answers from the class, sent to me
\n<\/span><\/a><\/p>\n

Required text:<\/b> Organic Chemistry, 7th edition, Francis A. Carey<\/p>\n

Student Solutions Manual to accompany Organic Chemistry, 7th Ed., Robert C. Atkins & Francis A. Carey (optional)<\/p>\n

Other Optional Study Guides (available in the Bookstore):<\/b><\/p>\n

\n
Organic Chemistry, 2nd Ed. (Schaum Outline Series)<\/dd>\n
3000 Solved Problems in Organic Chemistry (Schaum’s Solved
\nProblem Series)<\/dd>\n
Organic Chemistry (REA Problem Solvers)<\/dd>\n<\/dl>\n

Lab Text (required): <\/b>The Organic Chem Lab Survival Manual,
\nJ. W. Zubrick<\/p>\n

Class pak (Campus Copy)<\/p>\n

Laboratory Notebook (Hayden-McNeil)<\/p>\n

Safety Goggles<\/p>\n

Molecular Models:<\/b> Organic chemistry is a three dimensional
\nscience. Molecular models are highly recommended for lecture and
\nmay be purchased from the Student Affiliates of the American Chemical
\nSociety:<\/p>\n

\n
Organic Chemistry Models (Molecular Design, Inc.) $30.00<\/dd>\n
<\/dd>\n<\/dl>\n

Office Hours:<\/b> M, W: 10:00-11:00 am; T, R: 1:00 pm -2:00
\npm and by appointment. Office hours are subject to change or
\ncancellation without prior announcement.<\/p>\n

Drop-in hours with Dr. James Lowe (SC 7921, jim.lowe@vanderbilt.edu): M, W: 9:15-11:30 am ; T, R: 1:30 pm -4:30
\npm<\/p>\n

Course Content:<\/b> Chapters 1-12, 14, 15.1-15.13 of Carey, see tentative class schedule below.<\/p>\n

Course Policies:<\/b><\/p>\n

Exams: 3 seventy-five minute exams (100 points each)<\/p>\n

1 two-hour final exam (150 points)<\/p>\n

The final grades will be determined as follows:<\/p>\n

Three Exams (67% of final grade)<\/p>\n

Two-hour final Exam (33% of final grade)<\/p>\n

Grades: 90-100= A range; 80-89= B range; 70-79= C range; 60-69=
\nD range; below 60= F<\/p>\n

Exam dates are indicated on the accompanying schedule and will
\nNOT<\/b> be changed.<\/p>\n

Final Exam:<\/b> The final exam date is Wed. Dec. 16, 2009 at 9:00-11:00 am in room SC 4309. There will be NO<\/b> alternative date offered.
\nPlease make your travel plans accordingly.<\/p>\n

Make Up Exams:<\/b> I will give make-up exams under the following
\nconditions:<\/p>\n

\n
1. If it can be made up before the next scheduled class period.<\/dd>\n
2. If it is arranged prior to the day of the missed exam.<\/dd>\n
3. There is a legitimate medical or family excuse. These
\nexcuses must be verified in writing by the Dean’s office for
\nfamily reasons or a physician for illness. A note stating that
\nyou visited Student Health is not sufficient. Having other exams
\non the same day nor anxiety attacks will not be considered.<\/dd>\n<\/dl>\n

If all three of these condition cannot be met and you have
\nan excusable absence from the exam then your final exam will count
\nfor a proportionally larger portion of the total grade. It is
\nto your advantage to take all exams.<\/p>\n

A note on partial credit:<\/strong> Simply writing down an answer does
\nnot entitle you to partial credit. The answer must first be at
\nleast partially correct; second, it must be relevant to the question
\nbeing asked. Writing down the answer to a question that is not
\nbeing asked does not warrant partial credit.<\/p>\n

Honor Pledge:<\/b> You must legibly write the Vanderbilt
\nHonor Pledge on every exam. Writing the honor pledge acknowledges
\nthat you are committed to it. Exams which do not have the honor
\npledge will not be graded and you will receive a zero.<\/p>\n

“I pledge my honor that I have neither given nor received
\naid on this examination”<\/b><\/i><\/p>\n

A Helpful Hint:<\/b> There is a tremendous volume of information
\nto be covered in this course and we will need to proceed at a
\nbrisk pace. I suggest that you come to class prepared, having
\nalready read the chapter. This will allow you to concentrate on
\nconcepts that may be unclear to you. Chemistry is a problem solving
\noriented subject, thus I suggest that you try every problem in
\nthe chapters we cover ( you may see some of them reappear on exams).
\nFinally, come to class !! Important concepts, i.e. thing that
\nmay appear on exams, are emphasized in lecture as well as things
\nnot covered in the book. This course is challenging; be prepared
\nto dedicate at least 2 hours per night (10 hrs\/wk) on organic
\nchemistry.<\/p>\n

Letters of Recommendation:<\/b> I am willing to write you
\na honest letters of recommendation. Request for letters should
\nbe made at least one month before they are due. Requests
\nfor letters for early admissions to Vanderbilt Medical School
\nmust be made before Spring Break.<\/p>\n

Review from General Chemistry:<\/b> It is assumed that you
\nhave mastered the material taught in General Chemistry. In particular,
\nplease review the following topics.<\/p>\n

Text: “Chemistry: A Molecular Approach”, Nivaldo J. Tro
\nPearson Prentice Hall Publishing: 2008<\/p>\n

Electronic Structure: Chapter 8
\nLewis Structure and Chemical Bonds: Chapter 9
\nVSEPR and Molecular Orbitals: Chapter 10
\nAtomic Orbitals: Chapter 7
\nChemical Equilibrium: Chapter 14
\nAcid-Base Equilibrium: Chapters 15 and 16
\nThermochemistry: Chapters 6 and 17<\/p>\n

As the course progresses there will be some important numbers
\nand equations you will be expected to commit to memory. These
\nwill be explicitly pointed out to you. You should already know
\nthe following from General Chemistry.<\/p>\n

The Gas Law Constant, R= 1.99 cals\/(mol)(\u00b0K) (2.0 is close enough) -or- = 8.314 J\/(mol)(\u00b0K)<\/p>\n

Gibb’s Free Energy: \u0394G\u00b0= \u0394H\u00b0 – T\u0394S\u00b0<\/p>\n

\u0394G\u00b0= -RT ln Keq<\/p>\n

pKa= – log Ka<\/p>\n

In addition, it is also assumed that you know the vocabulary of General Chemistry. That is, you should know the names, structures, and charges of the common anions (see Tables 3-3 and 3-5, pg. 94-95 of Tro) and the names and structures of common mineral acids (see Table 15.1, pg. 664 of Tro) and bases (see Table 15.2, pg. 666 of Tro)<\/p>\n

\ufffd<\/p>\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n
\n
\n

Tentative class schedule<\/p>\n<\/div>\n<\/td>\n<\/tr>\n

\u00a0Thur., Aug. 27<\/td>\n\u00a0Chapter 1: Structure Determines Properties<\/td>\n \u00a0Slides for Chapter 1<\/strong>: pdf<\/a> ; ppt<\/a><\/p>\n

\u00a0<\/strong>Problems: 1-18, 20-27, 29, 31, 32, 36, 38-44, 46-50, 52-54, 58, 61-64, 68, 69, 71<\/td>\n<\/tr>\n

\u00a0Tue., Sept. 1<\/td>\n\u00a0Chapter 2: Alkanes and Cycloalkanes: Introduction to Hydrocarbons<\/td>\n \u00a0Slides for Chapter 2<\/strong>: pdf<\/a> ; ppt<\/a><\/p>\n

\u00a0<\/strong>Problems: 1, 2, 4, 5, 7-11, 13, 14, 17-23, 25-29, 42, 43, 45<\/p>\n

Orbital hybridization animation<\/a> (courtesy of Dr. Ian Hunt, Univ of Calgary)<\/td>\n<\/tr>\n

\u00a0Thur., Sept. 3<\/td>\n\u00a0Chapter 3: Alkanes and Cycloalkanes: Conformations and cis-trans<\/i> Stereoisomers<\/td>\n\u00a0Slides for Chapter 3<\/strong>: pdf<\/a> ; ppt<\/a><\/p>\n

\u00a0<\/strong>Problems: 1-10, 12, 15, 17-22, 24-26, 29, 30, 36, 39<\/td>\n<\/tr>\n

\u00a0Tue., Sept. 8<\/td>\n\u00a0Chapter 3: (con’t)<\/td>\n\u00a0<\/strong>Newman projections of ethane, propane and butane<\/a> (animated gifs)<\/p>\n

\u00a0<\/strong>Energetics of the rotation of ethane<\/a>, rotation of butane<\/a>, and a chair-chair interconversion<\/a>
\n(courtesy of Dr. Ian Hunt, Univ of Calgary)<\/td>\n<\/tr>\n

\u00a0Thur., Sept. 10<\/td>\n<\/i>\u00a0Chapter 4: Alcohols and Alkyl Halides<\/td>\n\u00a0Slides for Chapter 4<\/strong>: pdf<\/a> ; ppt<\/a><\/p>\n

\u00a0<\/strong>Problems: 1-18, 20-22, 25, 28, 34-43, 48, 50, 52, 53<\/td>\n<\/tr>\n

\u00a0Tue., Sept. 15<\/td>\n\u00a0Chapter 4: (con’t)<\/td>\n<\/td>\n<\/tr>\n
\u00a0Thur., Sept. 17<\/td>\n\u00a0Exam 1, Chapters 1-4<\/b><\/td>\n\u00a0Exam 1<\/a>\u00a0\/<\/strong> answers<\/a><\/p>\n

distribution<\/a><\/td>\n<\/tr>\n

\u00a0Tue., Sept. 22<\/td>\n\u00a0Chapter 5: Structure and Preparation of Alkenes: Elimination Reactions<\/td>\n\u00a0Slides for Chapter 5<\/strong> (revised 9\/23\/09): pdf<\/a> ; ppt<\/a>\u00a0<\/strong><\/p>\n

Problems: 1-5, 7-12, 14-22, 24-27, 29-31, 33-40, 42, 45-49<\/td>\n<\/tr>\n

\u00a0Thur., Sept. 24<\/td>\n\u00a0Chapter 5: (con’t)<\/td>\n<\/td>\n<\/tr>\n
\u00a0Tue., Sept. 29<\/td>\n\u00a0Chapter 6: Addition Reactions of Alkenes<\/td>\n\u00a0Slides for Chapter 6<\/strong> (updated 9\/27\/09): pdf<\/a> ; ppt<\/a>\u00a0<\/strong><\/p>\n

Problems: 1-8, 11, 12, 16, 18-20, 22-24, 26-29, 31, 32, 34, 36-39, 41, 43, 47, 57-60, 62<\/td>\n<\/tr>\n

\u00a0<\/b>Thur., Oct. 1<\/td>\n\u00a0Chapter 6: (con’t)<\/td>\n\u00a0Reactions of alkenes summary<\/a><\/td>\n<\/tr>\n
\u00a0Tue., Oct. 6<\/td>\n\u00a0Chapter 7: Stereochemistry<\/td>\n\u00a0Slides for Chapter 7<\/strong> (updated 10\/02\/09): pdf<\/a> ; ppt<\/a>\u00a0<\/strong><\/p>\n

Problems: 1-15, 17, 18, 20, 21, 23, 26, 28-31, 33, 35-38, 40, 42<\/td>\n<\/tr>\n

\u00a0Thur., Oct. 8<\/td>\n\u00a0Chapter 7: (con’t)<\/td>\n<\/td>\n<\/tr>\n
\u00a0<\/i>Tue., Oct. 13<\/td>\n\u00a0Chapter 8: Nucleophilic Substitution<\/td>\n\u00a0Slides for Chapter 8<\/strong> (revised 10\/15\/09): pdf<\/a> ; ppt<\/a>\u00a0<\/strong><\/p>\n

Problems: 1-13, 15-19, 21, 25, 29-34, 37, 38<\/p>\n

summary of nucleophilic subsititution<\/a><\/td>\n<\/tr>\n

\u00a0Thur., Oct. 15<\/td>\n\u00a0Chapter 8: (con’t)<\/td>\n\u00a0(mid-semester deficiency report due)<\/td>\n<\/tr>\n
<\/i>\u00a0Tue., Oct. 20<\/td>\n\u00a0Exam 2, Chapters 1-8<\/b><\/td>\n\u00a0Exam 2<\/a>\u00a0\/<\/strong> answers<\/a><\/p>\n

distribution<\/a><\/td>\n<\/tr>\n

\u00a0Oct. 22-23<\/i><\/td>\n\u00a0October Break- no class<\/i><\/b><\/td>\n<\/td>\n<\/tr>\n
\u00a0Tue., Oct. 27<\/td>\n\u00a0Chapter 9: Alkynes<\/td>\n\u00a0Slides for Chapter 9<\/strong>: pdf<\/a> ; ppt<\/a>\u00a0<\/strong><\/p>\n

Problems: 2, 4-18, 20-29, 31-34<\/p>\n

Reactions of alkynes summary<\/a><\/td>\n<\/tr>\n

\u00a0Thur., Oct. 29<\/td>\n\u00a0Chapter 10: Conjugatation in Alkadienes and Allylic Systems<\/td>\n\u00a0Slides for Chapter 10<\/strong> (updated 10\/28\/09): pdf<\/a> ; ppt<\/a>\u00a0<\/strong><\/p>\n

Problems: 1, 3-19, 21-23, 26-31, 33-35, 39, 40<\/td>\n<\/tr>\n

\u00a0Tue., Nov. 3<\/td>\n\u00a0Chapter 10: (con’t)<\/td>\n<\/td>\n<\/tr>\n
\u00a0Thur., Nov. 5<\/td>\n\u00a0Chapter 11: Arenes and Aromaticity<\/td>\n\u00a0Slides for Chapter 11<\/strong> (updated 11\/4\/09): pdf<\/a> ; ppt<\/a>\u00a0<\/strong><\/p>\n

Problems: 1-14, 16, 18, 19, 21-24, 27-31, 33-38, 40-44, 48, 50, 52<\/td>\n<\/tr>\n

\u00a0Tue., Nov. 10<\/td>\n\u00a0Chapter 11: (con’t)<\/td>\n<\/td>\n<\/tr>\n
\u00a0Thur., Nov 12<\/td>\n\u00a0Chapter 12: Reactions of Arenes: Electrophilic Aromatic Substitution<\/td>\n\u00a0Slides for Chapter 12 <\/strong>(revised 11\/12\/09)<\/strong>: pdf<\/a> ; ppt<\/a>\u00a0<\/strong><\/p>\n

Problems: 1-8, 10, 12-21, 24-36, 39<\/td>\n<\/tr>\n

\u00a0Tue., Nov. 17<\/td>\n\u00a0Chapter 12: (con’t)<\/td>\n\u00a0Summary of electrophilic aromatic substitution<\/a>\u00a0<\/strong>\u00a0<\/strong><\/p>\n

synthesis of 5-chloro-2-nitropropylbenzene<\/a><\/td>\n<\/tr>\n

\u00a0Thur., Nov. 19<\/td>\n\u00a0Exam 3, Chapters 1-12<\/b><\/td>\n\u00a0Exam 3<\/a>\u00a0\/<\/strong> answers<\/a><\/p>\n

distribution<\/a><\/td>\n<\/tr>\n

\u00a0Nov 21-Nov <\/i>29<\/td>\n\u00a0Thanksgiving Break – no classes<\/i><\/b><\/td>\n<\/td>\n<\/tr>\n
\u00a0Tue., Dec. 1<\/td>\n\u00a0Chapter 14.1-14.13: Organometallic Compounds<\/td>\n\u00a0Slides for Chapter 14<\/strong>: pdf<\/a> ; ppt<\/a>\u00a0<\/strong><\/p>\n

Problems: 1-12, 17, 19, 21-30, 32, 37<\/td>\n<\/tr>\n

\u00a0Thur., Dec. 3<\/td>\n\u00a0Chapter 14.1-14.13: (con’t)<\/td>\n\u00a0Reactions of alkenes summary<\/a>\u00a0\u00a0(updated)<\/td>\n<\/tr>\n
\u00a0Tue., Dec. 8<\/td>\n\u00a0Chapter 15.1-15.13: Alcohols, Diols, and Thiols<\/td>\n\u00a0Slides for Chapter 15<\/strong>: pdf<\/a> ; ppt<\/a>\u00a0<\/strong><\/p>\n

Problems: 1-6, 8-10, 12, 14-16, 18-30, 32-38, 41<\/td>\n<\/tr>\n

\u00a0Thur., Dec. 10<\/td>\n <\/b>\u00a0Chapter 15.1-15.13: (con’t)<\/td>\n\u00a0organic synthesis problems<\/a> (answers<\/a>)<\/td>\n<\/tr>\n
\u00a0Wed. Dec. 16,<\/b> 9:00 – 11:00 am<\/b><\/td>\n\u00a0Final Exam, SC 4309, Chapter 1-12, 14.1-14.13, 15.1-15.13<\/b><\/td>\n<\/td>\n<\/tr>\n
<\/td>\n<\/td>\n<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

Suggested Problems: <\/b>Listed are representative problems from each chapter. Organic Chemistry is a problem solving oriented course. It is suggested that you work all the problems in each chapter and more if possible. Working problems will enhance your ability to do well on exams.<\/p>\n

Chapter 1 Problems: 1-18, 20-27, 29, 31, 32, 36, 38-44, 46-50, 52-54, 58, 61-64, 68, 69, 71<\/p>\n

Chapter 2 Problems: 1, 2, 4, 5, 7-11, 13, 14, 17-23, 25-29, 42, 43, 45<\/p>\n

Chapter 3 Problems: 1-10, 12, 15, 17-22, 24-26, 29, 30, 36, 39<\/p>\n

Chapter 4 Problems: 1-18, 20-22, 25, 28, 34-43, 48, 50, 52, 53<\/p>\n

Chapter 5 Problems: 1-5, 7-12, 14-22, 24-27, 29-31, 33-40, 42, 45-49<\/p>\n

Chapter 6 Problems: 1-8, 11, 12, 16, 18-20, 22-24, 26-29, 31, 32, 34, 36-39, 41, 43, 47, 57-60, 62<\/p>\n

Chapter 7 Problems: 1-15, 17, 18, 20, 21, 23, 26, 28-31, 33, 35-38, 40, 42<\/p>\n

Chapter 8 Problems: 1-13, 15-19, 21, 25, 29-34, 37, 38<\/p>\n

Chapter 9 Problems: 2, 4-18, 20-29, 31-34<\/p>\n

Chapter 10 Problems: 1, 3-19, 21-23, 26-31, 33-35, 39, 40<\/p>\n

Chapter 11 Problems: 1-14, 16, 18, 19, 21-24, 27-31, 33-38, 40-44, 48, 50, 52<\/p>\n

Chapter 12 Problems: 1-8, 10, 12-21, 24-36, 39<\/p>\n

Chapter 14 Problems: 1-12, 17, 19, 21-30, 32, 37<\/p>\n

Chapter 15 Problems: 1-6, 8-10, 12, 14-16, 18-30, 32-38, 41<\/p>\n

 <\/p>\n

Exams from Fall 1997<\/b><\/p>\n

\n
Exam 1<\/a> (answers<\/a>)<\/dd>\n
<\/dd>\n
Quiz<\/a> (answers<\/a>)<\/dd>\n
<\/dd>\n
Exam 2<\/a> (answers<\/a>)<\/dd>\n
<\/dd>\n
Quiz <\/a>(answers<\/a>)<\/dd>\n
<\/dd>\n
organic synthesis problems<\/a> (answers<\/a>)<\/dd>\n
<\/dd>\n
Exam 3 <\/a>(answers<\/a>)<\/dd>\n
<\/dd>\n
Combine Spectroscopy Problems<\/a> (answers<\/a>)<\/dd>\n<\/dl>\n

Some Useful Links<\/b><\/p>\n\n\n\n\n\n\n\n\n\n\n\n\n
Organic
\nChemistry OnLine Tutorial<\/a><\/td>\n		Chemistry
\nConcepTests<\/a><\/td>\n<\/tr>\n
Web-sters
\nOrganic Chemistry<\/a><\/td>\n		Eductional
\nMaterial for Organic Chemistry<\/a><\/td>\n<\/tr>\n
IUPAC
\nNomenclature of Organic Chemistry<\/a><\/td>\n		Organic Chemistry Practice Problems<\/a><\/td>\n<\/tr>\n
\u00a0CFCC ORGANIC CHEMISTRY<\/a><\/td>\n\u00a0Colby
\nCollege Organic Chemistry Resource Page<\/a><\/td>\n<\/tr>\n
Electronic
\nFlashcards of Organic Reactions<\/a><\/td>\n		Virtual Textbook of Organic Chemistry<\/a><\/td>\n<\/tr>\n
Organic Chemistry Help!!<\/a><\/td>\n\u00a0Organic Reactions: Movies<\/a><\/td>\n<\/tr>\n
OCHeM.com\u00a0<\/a><\/td>\n\n
\n\n
\n\n
\n\n
Organic Stereochemistry<\/a><\/div>\n<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n","protected":false},"excerpt":{"rendered":"

\u00a0Chem 220A: Section 1 Organic Chemistry Lecture (Fall 2009) T, R: 9:35 – 11:00 AM SC 4309 Carmelo J. Rizzo office: SC 7662 Tel.: 322-6100 e-mail: c.j.rizzo@vanderbilt.edu The Final Exam will be held on Wednesday, December 16 from 9:00 – 11:00 am in room SC 4309. No alternative final exam date will be offered. Office…<\/p>\n","protected":false},"author":272,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"page_onecolumn.php","meta":[],"tags":[],"_links":{"self":[{"href":"https:\/\/wp0.vanderbilt.edu\/rizzolab\/wp-json\/wp\/v2\/pages\/605"}],"collection":[{"href":"https:\/\/wp0.vanderbilt.edu\/rizzolab\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/wp0.vanderbilt.edu\/rizzolab\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/wp0.vanderbilt.edu\/rizzolab\/wp-json\/wp\/v2\/users\/272"}],"replies":[{"embeddable":true,"href":"https:\/\/wp0.vanderbilt.edu\/rizzolab\/wp-json\/wp\/v2\/comments?post=605"}],"version-history":[{"count":19,"href":"https:\/\/wp0.vanderbilt.edu\/rizzolab\/wp-json\/wp\/v2\/pages\/605\/revisions"}],"predecessor-version":[{"id":656,"href":"https:\/\/wp0.vanderbilt.edu\/rizzolab\/wp-json\/wp\/v2\/pages\/605\/revisions\/656"}],"wp:attachment":[{"href":"https:\/\/wp0.vanderbilt.edu\/rizzolab\/wp-json\/wp\/v2\/media?parent=605"}],"wp:term":[{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/wp0.vanderbilt.edu\/rizzolab\/wp-json\/wp\/v2\/tags?post=605"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}